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  • Title: An efficient synthesis of fluorinated azaheterocycles by aminocyclization of alkenes.
    Author: Huang HT, Lacy TC, Błachut B, Ortiz GX, Wang Q.
    Journal: Org Lett; 2013 Apr 19; 15(8):1818-21. PubMed ID: 23544433.
    Abstract:
    A general and efficient approach to important fluorinated azaheterocycles has been developed by incorporating nucleophilic fluorination into alkene difunctionalization. This intramolecular aminofluorination transformation of alkenes has been achieved via the aminocyclization of reactive unsaturated N-iodoamines, which can be generated in situ from either unsaturated N-chloramines or their amine precursors in a one-pot protocol.
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