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  • Title: Novel Co-based metal-organic frameworks and their magnetic properties using asymmetrically binding 4-(4'-carboxyphenyl)-1,2,4-triazole.
    Author: Aharen T, Habib F, Korobkov I, Burchell TJ, Guillet-Nicolas R, Kleitz F, Murugesu M.
    Journal: Dalton Trans; 2013 Jun 07; 42(21):7795-802. PubMed ID: 23552301.
    Abstract:
    Two novel Co-based metal-organic frameworks (MOFs) were synthesised and characterised using an asymmetrically binding ligand, 4-(4'-carboxyphenyl)-1,2,4 triazole (Hcpt). The isolated [Co3(II)(μ3-O)(OH)(cpt)3(H2O)2]n·xH2O·yDMF, Co-MOF1, exhibits a rhombohedral crystal structure (space group, P63/mc), with a trinuclear cobalt core that resembles the MIL88 series. This MOF shows paramagnetic behaviour down to 2 K with no saturation of magnetisation up to 7 T. This is presumably due to a geometrically frustrated triangular arrangement of Co spins. The two-dimensional complex, [Co(II)(cpt)(N3)]n, Co-MOF2, crystallises in a monoclinic crystal system (space group, C2/m). The magnetic measurements reveal metamagnetic behaviour for this complex with a critical field in the range of 700-1000 Oe.
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