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  • Title: Synthesis and reactivity of unsymmetrical azomethine imines formed using alkene aminocarbonylation.
    Author: Gan W, Moon PJ, Clavette C, Das Neves N, Markiewicz T, Toderian AB, Beauchemin AM.
    Journal: Org Lett; 2013 Apr 19; 15(8):1890-3. PubMed ID: 23565796.
    Abstract:
    Complex cyclic azomethine imines possessing a β-aminocarbonyl motif can be accessed readily from simple alkenes and hydrazones. This alkene aminocarbonylation approach allows formation of ketone-derived azomethine imines of unprecedented complexity. Since unsymmetrical hydrazones are used, two stereoisomers are formed: the reactivity of chiral derivatives is explored in both intra- and intermolecular systems.
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