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  • Title: Stereoselective titanium-mediated aldol reactions of a chiral isopropyl ketone.
    Author: Zambrana J, Romea P, Urpí F.
    Journal: Chem Commun (Camb); 2013 May 18; 49(40):4507-9. PubMed ID: 23576096.
    Abstract:
    A novel substrate-controlled aldol reaction of a chiral isopropyl ketone is reported. The outstanding regioselective enolization by TiCl4-i-Pr2NEt provides a chelated enolate that can participate in highly diastereoselective additions to a wide array of aldehydes favouring the corresponding 2,5-syn adducts.
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