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  • Title: An efficient method to separate Sc3N@C80 Ih and D5h isomers and Sc3N@C78 by selective oxidation with acetylferrocenium [Fe(COCH3C5H4)Cp]+.
    Author: Cerón MR, Li FF, Echegoyen L.
    Journal: Chemistry; 2013 Jun 03; 19(23):7410-5. PubMed ID: 23576321.
    Abstract:
    Based on the different oxidation potentials of endohedral fullerenes Sc3N@C80 Ih and D5h and Sc3N@C78, an efficient and useful method that avoids HPLC has been developed for their separation. Selective chemical oxidation of the Sc3N@D5h-C80 isomer and Sc3N@C78 by using an acetylferrocenium salt [Fe(COCH3C5H4)Cp](+) followed by column chromatographic separation and reduction with CH3SNa resulted in the isolation of pure Sc3N@Ih-C80, Sc3N@C78, and a mixture of Sc3N@D5h-C80 and Sc3N@C68.
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