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  • Title: Synthesis of the 10-azatricyclo[3.3.2.0(4,8)]decane core of C20-diterpenoid alkaloid racemulsonine via iodine(III) promoted transannular aziridination reaction.
    Author: Mei RH, Liu ZG, Cheng H, Xu L, Wang FP.
    Journal: Org Lett; 2013 May 03; 15(9):2206-9. PubMed ID: 23587046.
    Abstract:
    The functionalized A/E/F ring system of C20-diterpenoid alkaloid racemulsonine has been efficiently synthesized. The Key steps involved a diastereoselective Au(I)-catalyzed annulation to form cis-fused cyclopentene and a PIDA promoted transannular aziridination of primary amine followed by regio- and stereoselective ring cleavage of bridged aziridine.
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