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  • Title: Synthesis of cyclic 1-alkenylboronates via Zr-mediated double functionalization of alkynylboronates and sequential Ru-catalyzed ring-closing olefin metathesis.
    Author: Nishihara Y, Suetsugu M, Saito D, Kinoshita M, Iwasaki M.
    Journal: Org Lett; 2013 May 17; 15(10):2418-21. PubMed ID: 23631488.
    Abstract:
    Synthesis of novel cyclic 1-alkenylboronates is accomplished through the zirconium-mediated regio- and stereoselective double functionalization of 1-alkynylboronates and the subsequent ruthenium-catalyzed ring-closing metathesis (RCM). The obtained substituted cyclic 1-alkenylboronates are transformed into o-terphenyl and triphenylene derivatives.
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