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Title: Large scale preparation of graphene quantum dots from graphite with tunable fluorescence properties. Author: Sun Y, Wang S, Li C, Luo P, Tao L, Wei Y, Shi G. Journal: Phys Chem Chem Phys; 2013 Jun 28; 15(24):9907-13. PubMed ID: 23673490. Abstract: We report an improved Hummers method for synthesizing graphene quantum dots (GQDs) by directly oxidizing and etching graphite powders. The yield of GQDs is as high as 63 ± 7% (by weight, wt%), suggesting this technique is suitable for producing GQDs on a large scale. The GQDs are nanocrystals with lateral dimensions in the range of 2-4 nm and an average thickness of around 1.3 nm. The emission peaks of as-prepared GQDs can be tuned in the range of 440 to 510 nm by varying the reaction conditions. Their fluorescence quantum yields were tested to be around 1%, which could be further increased to about 3% by hydrothermal treatment. These GQDs have low cytotoxicity and excellent biocompatibility, indicating that they are promising for biological applications.[Abstract] [Full Text] [Related] [New Search]