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  • Title: Stereoselective direct reductive amination of ketones with electron-deficient amines using Re2O7/NaPF6 catalyst.
    Author: Das BG, Ghorai P.
    Journal: Org Biomol Chem; 2013 Jul 14; 11(26):4379-82. PubMed ID: 23703396.
    Abstract:
    The first example of direct reductive amination (DRA) of ketones with electron-deficient amines (EDA) such as Cbz-, Boc-, EtOCO-, Fmoc-, Bz-, ArSO2-, etc. protected amines have been achieved using catalytic Re2O7/NaPF6. Excellent chemoselectivities as well as diastereoselectivity (for 2-alkyl cyclohexanones) were obtained.
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