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  • Title: Interaction of hemoglobin with three ligans: organic phosphates and the Bohr effect.
    Author: Benesch RE, Rubin H.
    Journal: Proc Natl Acad Sci U S A; 1975 Jun; 72(6):2465-7. PubMed ID: 237273.
    Abstract:
    The assumption that the Bohy coefficient (less than log p 50)/(less than pH) is equal to the haldane coefficient (less than h minus plus) of hemoglobin is shown to be incorrect in the presence of allosteric effectors such as 2,3-diphosphoglycerate. The theoretical relation between the two coefficients in the presence of 2.3-diphosphoglycerate as derived. Experimental data on the variation of both coefficients with diphosphoglycerate concentration are presented and shown to be in agreement with prediction.
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