These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Asymmetric, protecting-group-free total synthesis of (+)-caribenol A.
    Author: Han JC, Liu LZ, Li CC, Yang Z.
    Journal: Chem Asian J; 2013 Sep; 8(9):1972-5. PubMed ID: 23761011.
    Abstract:
    Caribenol Queen: A new asymmetric, protecting-group-free synthesis of the marine tetracyclic diterpenoid (+)-caribenol A (1) has been achieved. The enantioselective synthesis employed (S)-methyl 1-methyl-2-oxocyclopent-3-enecarboxylate as a chiral scaffold, and an intramolecular Diels-Alder (IMDA) reaction of substrate 3 afforded the [5.7.6] tricyclic core in compound 2.
    [Abstract] [Full Text] [Related] [New Search]