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  • Title: Direct synthesis of pyridines and quinolines by coupling of γ-amino-alcohols with secondary alcohols liberating H2 catalyzed by ruthenium pincer complexes.
    Author: Srimani D, Ben-David Y, Milstein D.
    Journal: Chem Commun (Camb); 2013 Jul 28; 49(59):6632-4. PubMed ID: 23771175.
    Abstract:
    A novel, one-step synthesis of substituted pyridine- and quinoline-derivatives was achieved by acceptorless dehydrogenative coupling of γ-aminoalcohols with secondary alcohols. The reaction involves consecutive C-N and C-C bond formation, catalyzed by a bipyridyl-based ruthenium pincer complex with a base.
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