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  • Title: Anion-directed assembly of a non-interpenetrated square-grid metal-organic framework with nanoscale porosity.
    Author: Mitra A, Hubley CT, Panda DK, Clark RJ, Saha S.
    Journal: Chem Commun (Camb); 2013 Jul 28; 49(59):6629-31. PubMed ID: 23775140.
    Abstract:
    A non-interpenetrated square grid metal-organic framework (MOF) comprised of octahedral Zn(II) ions and linear N,N'-di(4-pyridyl)-1,4,5,8-naphthalenediimide (DPNDI) ligands was formed in the presence of noncoordinating perchlorate counterions that occupied the cavities of the porous network by forming CH···anion hydrogen bonds with DPNDI ligands, whereas a linear coordination polymer was obtained when Zn(II)-coordinated nitrate ions were present as counterions.
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