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  • Title: One-dimensional self-assembly of a water soluble perylene diimide molecule by pH triggered hydrogelation.
    Author: Datar A, Balakrishnan K, Zang L.
    Journal: Chem Commun (Camb); 2013 Aug 07; 49(61):6894-6. PubMed ID: 23800954.
    Abstract:
    A water soluble perylene diimide molecule has been fabricated into nanofibers via a pH triggered hydrogelation route. The one-dimensional self-assembly is dominated by the intermolecular π-π stacking interactions in concert with the hydrogen bonding between the carboxylic acid side chains. The anisotropic electronic and optical properties observed for the nanofibers are consistent with the one-dimensional intermolecular π-π arrangement.
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