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  • Title: Rhodium-catalyzed boron arylation of 1,2-azaborines.
    Author: Rudebusch GE, Zakharov LN, Liu SY.
    Journal: Angew Chem Int Ed Engl; 2013 Aug 26; 52(35):9316-9. PubMed ID: 23832871.
    Abstract:
    UNLABELLED: BN isosteres of biphenyl compounds are prepared through Rh-catalyzed cross-coupling between 2-chloro-1,2-azaborines and arylstannanes (see scheme). The synthetic method should enable investigations of structure–activity relationships (SARs) by expanding the chemical space of the pharmaceutically relevant biphenyl structure through BN/CC isosterism.
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