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  • Title: Desymmetrization of bicyclo[3.n.1]-3-one derivatives by palladium-catalyzed asymmetric allylic alkylation.
    Author: Yu Y, Yang XF, Xu CF, Ding CH, Hou XL.
    Journal: Org Lett; 2013 Aug 02; 15(15):3880-3. PubMed ID: 23869571.
    Abstract:
    Desymmetrization of carbon nucleophiles by palladium-catalyzed asymmetric allylic alkylation has been realized for the first time. Products with three chiral centers were obtained in good yield and with high diastereo- and enantioselectivity. The method offers an efficient access to optically active tropane derivatives.
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