These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Reversible switching of the electronic ground state in a pentacoordinated Cu(II) complex.
    Author: Sasmal A, Saha S, Gómez-García CJ, Desplanches C, Garribba E, Bauzá A, Frontera A, Scott R, Butcher RJ, Mitra S.
    Journal: Chem Commun (Camb); 2013 Sep 14; 49(71):7806-8. PubMed ID: 23884406.
    Abstract:
    An easy reversible switching of the electronic ground state in a pentacoordinated copper(II) complex is reported for the first time. The simple protonation of a carboxylic group in a Cu(II) complex with a {dx(2)-y(2)}(1) electronic configuration leads to a flip of the ground electronic configuration from {dx(2)-y(2)}(1) to {dz(2)}(1) in the metal ion.
    [Abstract] [Full Text] [Related] [New Search]