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  • Title: Catalytic stereospecific alkylation of malononitriles with enantioenriched primary allylic amines.
    Author: Li MB, Li H, Wang J, Liu CR, Tian SK.
    Journal: Chem Commun (Camb); 2013 Sep 25; 49(74):8190-2. PubMed ID: 23939597.
    Abstract:
    An unprecedented alkylation reaction of malononitriles with enantioenriched primary allylic amines has been developed in a stereospecific manner through palladium-catalyzed sp(3) C-N bond cleavage without additives at room temperature.
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