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  • Title: Catalytic asymmetric construction of chiral hydropyridazines via conjugate addition of N-monosubstituted hydrazones to enones.
    Author: Wu W, Yuan X, Hu J, Wu X, Wei Y, Liu Z, Lu J, Ye J.
    Journal: Org Lett; 2013 Sep 06; 15(17):4524-7. PubMed ID: 23964662.
    Abstract:
    The first example of a highly enantioselective and scalable formal diaza-ene reaction between N-monosubstituted hydrazones and enones catalyzed by a simple chiral primary-second diamine salt has been developed. The catalytic process provides a highly practical and stereoselective synthetic method for chiral hydropyridazines.
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