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  • Title: Preparation of vinyl silyl ethers and disiloxanes via the silyl-Heck reaction of silyl ditriflates.
    Author: Martin SE, Watson DA.
    Journal: J Am Chem Soc; 2013 Sep 11; 135(36):13330-3. PubMed ID: 23984876.
    Abstract:
    Vinyl silyl ethers and disiloxanes can now be prepared from aryl-substituted alkenes and related substrates using a silyl-Heck reaction. The reaction employs a commercially available catalyst system and mild conditions. This work represents a highly practical means of accessing diverse classes of vinyl silyl ether substrates in an efficient and direct manner with complete regiomeric and geometric selectivity.
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