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  • Title: Direct construction of quaternary carbons from tertiary alcohols via photoredox-catalyzed fragmentation of tert-alkyl N-phthalimidoyl oxalates.
    Author: Lackner GL, Quasdorf KW, Overman LE.
    Journal: J Am Chem Soc; 2013 Oct 16; 135(41):15342-5. PubMed ID: 24074152.
    Abstract:
    A convenient method for the direct construction of quaternary carbons from tertiary alcohols by visible-light photoredox coupling of tert-alkyl N-phthalimidoyl oxalate intermediates with electron-deficient alkenes is reported.
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