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  • Title: Ir-catalyzed preparation of SF5-substituted potassium aryl trifluoroborates via C-H borylation and their application in the Suzuki-Miyaura reaction.
    Author: Joliton A, Carreira EM.
    Journal: Org Lett; 2013 Oct 18; 15(20):5147-9. PubMed ID: 24090251.
    Abstract:
    The preparation of new pentafluorosulfanyl-substituted potassium aryltrifluoroborates via Ir-catalyzed C-H borylation is reported. The utility of these novel building blocks was demonstrated in the Suzuki-Miyaura cross-coupling reaction, giving access to 3,5-disubstituted pentafluorosulfanylbenzenes.
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