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  • Title: Total synthesis of phenanthroindolizidine alkaloids through an amidyl radical cascade/rearrangement reaction.
    Author: Han G, Liu Y, Wang Q.
    Journal: Org Lett; 2013 Oct 18; 15(20):5334-7. PubMed ID: 24107089.
    Abstract:
    A short and general synthesis of the phenanthroindolizidine alkaloids is reported, featuring an unusual amidyl radical 5-exo/5-exo/rearrangement cascade of a xanthate precursor. Second, using an amidyl radical 5-exo/6-endo cascade to synthesize a phenanthroindolizidine alkaloid exclusively has been developed through a small structural modification.
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