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  • Title: Synthesis of isoquinolines via Rh(III)-catalyzed C-H activation using hydrazone as a new oxidizing directing group.
    Author: Chuang SC, Gandeepan P, Cheng CH.
    Journal: Org Lett; 2013 Nov 15; 15(22):5750-3. PubMed ID: 24156564.
    Abstract:
    An efficient and mechanistically interesting method for the synthesis of highly substituted isoquinolines by a Rh(III)-catalyzed hydrazone directed ortho C-H bond activation and annulation without an external oxidant is described. This reaction is accomplished via a C-C and C-N bond formation along with N-N bond cleavage.
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