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  • Title: An asymmetric normal-electron-demand aza-Diels-Alder reaction via trienamine catalysis.
    Author: Liu JX, Zhou QQ, Deng JG, Chen YC.
    Journal: Org Biomol Chem; 2013 Dec 21; 11(47):8175-8. PubMed ID: 24193264.
    Abstract:
    An asymmetric normal-electron-demand aza-Diels-Alder cycloaddition of 2-aryl-3H-indol-3-ones and 2,4-dienals was explored via trienamine catalysis of a chiral secondary amine. Multifunctional tricyclic polyhydropyrido[1,2-a]indoles were efficiently constructed in good stereoselectivity (up to 92% ee, >19 : 1 dr).
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