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  • Title: Highly enantioselective synthesis of tetrahydrocarbolines via iridium-catalyzed intramolecular Friedel-Crafts type allylic alkylation reactions.
    Author: Xu QL, Zhuo CX, Dai LX, You SL.
    Journal: Org Lett; 2013 Dec 06; 15(23):5909-11. PubMed ID: 24215126.
    Abstract:
    A highly enantioselective synthesis of substituted tetrahydrocarbolines via Ir-catalyzed Friedel-Crafts type intramolecular asymmetric allylic alkylation of 2-indolyl allyl carbonates has been developed. This strategy features excellent chemoselectivity and enantioselectivity, mild reaction conditions, and an easily accessed chiral ligand.
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