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  • Title: Indole synthesis by rhodium(III)-catalyzed hydrazine-directed C-H activation: redox-neutral and traceless by N-N bond cleavage.
    Author: Zhao D, Shi Z, Glorius F.
    Journal: Angew Chem Int Ed Engl; 2013 Nov 18; 52(47):12426-9. PubMed ID: 24222579.
    Abstract:
    Fishing for complements! There is an alternative to the useful Fischer indole synthesis. The new method utilizes the same retrosynthetic disconnection but is based on a Rh(III) -catalyzed directed CH activation step and a successive coupling with alkynes.
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