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  • Title: Enzyme- and ruthenium-catalyzed dynamic kinetic resolution of functionalized cyclic allylic alcohols.
    Author: Lihammar R, Millet R, Bäckvall JE.
    Journal: J Org Chem; 2013 Dec 06; 78(23):12114-20. PubMed ID: 24245668.
    Abstract:
    Enantioselective synthesis of functionalized cyclic allylic alcohols via dynamic kinetic resolution has been developed. Cyclopentadienylruthenium catalysts were used for the racemization, and lipase PS-IM or CALB was employed for the resolution. By optimization of the reaction conditions the formation of the enone byproduct was minimized, making it possible to prepare a range of optically active functionalized allylic alcohols in good yields and high ee's.
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