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  • Title: Facile synthesis of sandwiched Zn2GeO4-graphene oxide nanocomposite as a stable and high-capacity anode for lithium-ion batteries.
    Author: Zou F, Hu X, Qie L, Jiang Y, Xiong X, Qiao Y, Huang Y.
    Journal: Nanoscale; 2014 Jan 21; 6(2):924-30. PubMed ID: 24280782.
    Abstract:
    Traditional metal anode materials in lithium-ion batteries are plagued by instability upon discharge-charge cycling. We report that a unique sandwiched Zn2GeO4-graphene oxide nanocomposite has been synthesized on a large scale through a simple ion-exchange reaction, whereby Zn2GeO4 nanorods with lengths of 600 nm and widths of 40 nm are homogeneously sandwiched into the graphene oxide matrix. Compared with bare Zn2GeO4 nanorods, a dramatic improvement in the electrochemical performance of the resulting nanocomposite has been achieved. In the voltage window of 0.001-3 V, the electrode of the Zn2GeO4-graphene oxide nanocomposite delivers a specific capacity as high as 1150 mA h g(-1) at 200 mA g(-1) after 100 discharge-charge cycles. Even at a high current density of 3.2 A g(-1), a capacity of 522 mA h g(-1) can be retained. The unusual electrochemical performance including highly reversible capacity and excellent rate capability arise from synergetic chemical coupling effects between Zn2GeO4 and graphene oxide.
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