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Title: Dramatic synergistic effects between hydroquinone and resorcinol derivatives for the organocatalyzed reduction of dioxygen by diethylhydroxylamine. Author: Lebeuf R, Nardello-Rataj V, Aubry JM. Journal: Chem Commun (Camb); 2014 Jan 25; 50(7):866-8. PubMed ID: 24296880. Abstract: Diethylhydroxylamine reduces dioxygen in the presence of catalytic amounts of hydroquinone. A great improvement is achieved by adding resorcinol derivatives as co-catalysts. Though the formation of heterodimers does not seem to be the sole cause of the synergy, such products constitute a new class of powerful organocatalysts for dioxygen scavenging.[Abstract] [Full Text] [Related] [New Search]