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  • Title: A two-dimensional Cu(I) framework incorporating the 1-phenyl-1H-1,2,3,4-tetrazole-5-thiol ligand.
    Author: Zhou FX, Yue CY, Zhang HP, Lei XW.
    Journal: Acta Crystallogr C; 2013 Dec 15; 69(Pt 12):1478-81. PubMed ID: 24311494.
    Abstract:
    The new two-dimensional coordination polymer, poly[(μ4-1-phenyl-1H-1,2,3,4-tetrazole-5-thiolato)copper(I)], [Cu(C7H5N4S)]n, has been prepared under solvothermal conditions by reacting CuBr with 1-phenyl-1H-1,2,3,4-tetrazole-5-thiol (Hptt) in an acetonitrile and acetone solution. In the crystal structure, each Cu(I) ion is coordinated by two N atoms and two S atoms from four ptt(-) ligands, and each ptt(-) ligand links four Cu(I) ions to form two-dimensional layers which lie parallel to the (100) plane. These layers stack along the [100] direction via van der Waals interactions.
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