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  • Title: 2-{2-[4-(Dimethylamino)phenyl]-6-methyl-4H-pyran-4-ylidene}malononitrile: a colorimetric and fluorescent chemosensor for low pH values.
    Author: Kim DY, Kim JN, Kim HJ.
    Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2014 Mar 25; 122():304-8. PubMed ID: 24316545.
    Abstract:
    For developing intramolecular charge transfer (ICT) chemosensors for low pH values, 2-{2-[4-(dimethylamino)phenyl]-6-methyl-4H-pyran-4-ylidene}malononitrile (DPM) was designed and synthesized. The spectroscopic and pH-sensing properties of DPM were investigated by UV-Vis and fluorescence spectroscopy. This sensor exhibited a pH-dependent ratiometric absorption property in the range of pH 0-3, along with a reversible color change from yellow to colorless with increasing acid concentration. The fluorescence intensity of the sensor was increased with increasing pH within the pH range of 0-2.
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