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  • Title: Hybrid gold/chiral Brønsted acid relay catalysis allows an enantioselective synthesis of (-)-5-epi-eupomatilone-6.
    Author: Wu X, Li ML, Wang PS.
    Journal: J Org Chem; 2014 Jan 03; 79(1):419-25. PubMed ID: 24328038.
    Abstract:
    An enantioselective synthesis of (-)-5-epi-eupomatilone-6 has been accomplished by using relay catalytic cascade intramolecular hydrosiloxylation and Mukaiyama aldol reaction of 2,3,4-trimethoxy-6-(phenylethynyl)phenyl dimethylsilanol with fluorenylglyoxylate.
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