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  • Title: Copper-catalyzed trifluoromethylation of alkenes with an electrophilic trifluoromethylating reagent.
    Author: Wang XP, Lin JH, Zhang CP, Xiao JC, Zheng X.
    Journal: Beilstein J Org Chem; 2013; 9():2635-40. PubMed ID: 24367428.
    Abstract:
    An efficient method for the copper-catalyzed trifluoromethylation of terminal alkenes with an electrophilic trifluoromethylating reagent has been developed. The reactions proceeded smoothly to give trifluoromethylated alkenes in good to excellent yields. The results provided a versatile approach for the construction of Cvinyl-CF3 bonds without using prefunctionalized substrates.
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