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  • Title: Rhodium-catalyzed synthesis of isoquinolines and indenes from benzylidenehydrazones and internal alkynes.
    Author: Huang XC, Yang XH, Song RJ, Li JH.
    Journal: J Org Chem; 2014 Feb 07; 79(3):1025-31. PubMed ID: 24417252.
    Abstract:
    A new route is presented for the selective assembly of isoquinolines and indenes by rhodium-catalyzed tandem cyclization of benzylidenehydrazones with internal alkynes. This method involves the selective cleavage of the N-N bond and the C═N bonds and is dependent on the substituents of the benzylidenehydrazone.
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