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  • Title: Direct access to α-trifluoromethyl enones via efficient copper-catalyzed trifluoromethylation of Meyer-Schuster rearrangement.
    Author: Xiong YP, Wu MY, Zhang XY, Ma CL, Huang L, Zhao LJ, Tan B, Liu XY.
    Journal: Org Lett; 2014 Feb 07; 16(3):1000-3. PubMed ID: 24467612.
    Abstract:
    A novel domino copper-catalyzed trifluoromethylated Meyer-Schuster rearrangement reaction with Togni's reagent was developed, leading to α-trifluormethyl (CF3) enone products with moderate to good yields. Furthermore, α-CF3 enones can be transformed toward important trifluoromethyl heterocyclic motifs in a one-pot version.
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