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  • Title: Rhodium-catalyzed [2+2+2] cycloaddition of diynes with carbodiimides and carbon dioxide under ambient conditions.
    Author: Ishii M, Mori F, Tanaka K.
    Journal: Chemistry; 2014 Feb 17; 20(8):2169-74. PubMed ID: 24478189.
    Abstract:
    It has been established that a cationic rhodium(I)/H8-binap complex is able to catalyze the [2+2+2] cycloaddition of diynes with carbodiimides and carbon dioxide under ambient conditions. Enantio- and/or regioselective variants of these reactions are also disclosed.
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