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  • Title: An efficient synthesis of novel fused cycloheptatrienes through Mn(II)-mediated formal intermolecular [2 + 2 + 2 + 1] cycloaddition.
    Author: Shu WM, Ma JR, Yang Y, Wu AX.
    Journal: Org Lett; 2014 Mar 07; 16(5):1286-9. PubMed ID: 24564369.
    Abstract:
    A new method for manganous acetate tetrahydrate mediated formal intermolecular [2 + 2 + 2 + 1] cycloaddition was developed for the synthesis of fused cycloheptatriene derivatives from N-(acylmethyl)pyridinium iodides and naphthoquinone. This method provides an innovative route for the efficient and convenient construction of fused seven-membered carbocycles from simple starting materials.
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