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  • Title: Tetraphenylethylene-based expanded oxacalixarene: synthesis, structure, and its supramolecular grid assemblies directed by guests in the solid state.
    Author: Zhang C, Wang Z, Song S, Meng X, Zheng YS, Yang XL, Xu HB.
    Journal: J Org Chem; 2014 Mar 21; 79(6):2729-32. PubMed ID: 24575975.
    Abstract:
    A novel TPE-based expanded oxacalixarene with typical aggregation-induced emission properties was synthesized by the SNAr reaction of dihydroxytetraphenylethylene with 2,6-dichloropyrazine. The conformation of the oxacalixarene is adjusted by the encapsulated guests (benzene or THF), which results in different supramolecular grid structures in the solid state.
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