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Title: Synthesis of functionalized 2-vinyl-2,3-dihydropyrroles and 3-methylene-1,2,3,4-tetrahydropyridines by palladium-catalyzed cyclization of β-enaminocarbonyl compounds with allylic bisacetates. Author: Yoshida M, Kinoshita K, Namba K. Journal: Org Biomol Chem; 2014 Apr 21; 12(15):2394-403. PubMed ID: 24595409. Abstract: A palladium-catalyzed cyclization of β-enaminocarbonyl compounds with allylic bisacetates is described. 2-Vinyl-2,3-dihydropyrroles and 3-methylene-1,2,3,4-tetrahydropyridines were produced from the reaction of β-enaminocarbonyl compounds with 1,4-diacetoxy-2-butene and 2-methylene-1,3-propanediol diacetate, respectively.[Abstract] [Full Text] [Related] [New Search]