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  • Title: Iron cyclopentadienone complexes: discovery, properties, and catalytic reactivity.
    Author: Quintard A, Rodriguez J.
    Journal: Angew Chem Int Ed Engl; 2014 Apr 14; 53(16):4044-55. PubMed ID: 24644277.
    Abstract:
    Iron cyclopentadienone complexes have recently received particular attention in organic chemistry. This is due to their easy synthesis from simple and cheap materials, air-water stability, and most importantly for their unique catalytic features arising from the presence of a non-innocent ligand, triggering powerful redox properties. Herein we discuss the properties of such complexes from synthetic and mechanistic points of view, and their applications in original redox-neutral transformations in both racemic and enantioselective series.
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