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  • Title: Electrochemical redox responsive polymeric micelles formed from amphiphilic supramolecular brushes.
    Author: Feng A, Yan Q, Zhang H, Peng L, Yuan J.
    Journal: Chem Commun (Camb); 2014 May 11; 50(36):4740-2. PubMed ID: 24681929.
    Abstract:
    The end-decorated homopolymer poly(ε-caprolactone)-ferrocene threaded onto a β-cyclodextrin-functionalized main-chain polymer can form a class of amphiphilic noncovalent graft copolymers based on the host-guest interactions of the terminal groups on the side chains. These new supramolecular polymer brushes can further self-assemble into micellar aggregates that exhibit reversible assembly and disassembly behavior under an electrochemical redox trigger, which opens up a new route to building dynamic block copolymer topologies.
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