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  • Title: Efficient palladium-catalyzed aminocarbonylation of aryl iodides using palladium nanoparticles dispersed on siliceous mesocellular foam.
    Author: Tinnis F, Verho O, Gustafson KP, Tai CW, Bäckvall JE, Adolfsson H.
    Journal: Chemistry; 2014 May 12; 20(20):5885-9. PubMed ID: 24687938.
    Abstract:
    A highly dispersed nanopalladium catalyst supported on mesocellular foam (MCF), was successfully used in the heterogeneous catalysis of aminocarbonylation reactions. During the preliminary evaluation of this catalyst it was discovered that the supported palladium nanoparticles exhibited a "release and catch" effect, meaning that a minor amount of the heterogeneous palladium became soluble and catalyzed the reaction, after which it re-deposited onto the support.
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