These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Two Cu-complex directed aluminoborates: from 2D layers to 3D frameworks.
    Author: Cheng L, Zhao JW, Yang GY.
    Journal: Dalton Trans; 2014 May 21; 43(19):7324-30. PubMed ID: 24691751.
    Abstract:
    With transition metal complexes as the structure-directing agents, two novel aluminoborates with a 2D layer [Cu(enMe)2]3{Al2[B5O8(OH)2]4}·H2O (1, enMe = 1,2-diaminopropane) and a 3D open-framework [Cu(en)2][Al-B5O10] (2, en = ethylenediamine) have been solvothermally prepared and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, UV/Vis spectroscopy, powder and single-crystal X-ray diffraction. 1 is a 2D {Al[B5O8(OH)2]2}(3-) layer constructed by the alternate linkages of AlO4 groups and B5O8(OH)2 clusters. The 2D layer contains 16-member rings (MRs), showing a unique sql net topology. In 2, the AlO4 groups and B5O10 clusters alternately link together to form a 3D framework, in which the stacking of building layers is different. The copper centres are chelated by two amine ligands to form a square planar, which have weak axial interactions with the aluminoborate frameworks.
    [Abstract] [Full Text] [Related] [New Search]