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  • Title: Palladium-catalyzed C(sp²)-H arylation using formamide as a transformable directing group.
    Author: Wan C, Zhao J, Xu M, Huang J.
    Journal: J Org Chem; 2014 May 16; 79(10):4751-6. PubMed ID: 24762164.
    Abstract:
    A new process for the ortho arylation of formanilides through palladium-catalyzed C-H activation is described. Formamide is reported as a transformable directing group in the transition-metal-catalyzed C-H functionalization reaction. The resulting biarylformanilide products can be readily transformed to the corresponding biarylisocyanides or N-heterocycles.
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