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  • Title: A new pyrene-based Schiff-base: a selective colorimetric and fluorescent chemosensor for detection of Cu(II) and Fe(III).
    Author: Bhorge YR, Tsai HT, Huang KF, Pape AJ, Janaki SN, Yen YP.
    Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2014 Sep 15; 130():7-12. PubMed ID: 24769379.
    Abstract:
    A new receptor 1 was prepared, for the detection of Cu2+ and Fe3+ in solutions as a colorimetric and fluorescent sensor, respectively. Receptor 1 shows highly selective and sensitive recognition toward Cu2+ and Fe3+ by naked eye UV-Vis and fluorescent color changes in aqueous solution (DMSO/H2O=8/2, v/v), respectively. The sensitivity toward Cu2+ or Fe3+ was not interfered with by the presence of other metal ions such as Mg2+, Cd2+, Ag+, Zn2+, Ni2+, Co2+, Mn2+, Cr3+, Ca2+, Na+, Pb2+, K+, Fe2+, Li+ and Hg2+ ions. Receptor 1 can be used for semi-quantitative recognition of Cu2+ ions at ppm level. The fluorescence microscopy experiments showed that the receptor is efficient for detection of Fe3+ in vitro, developing a good image of the biological organelles.
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