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  • Title: Arylalkene synthesis via decarboxylative cross-coupling of alkenyl halides.
    Author: Tang J, Goossen LJ.
    Journal: Org Lett; 2014 May 16; 16(10):2664-7. PubMed ID: 24802529.
    Abstract:
    A bimetallic catalyst system generated from readily available palladium(II) and copper(I) salts, 1,10-phenanthroline and tri-1-naphthylphosphine was found to efficiently mediate the decarboxylative cross-coupling of alkenyl bromides and chlorides with aromatic carboxylates. It allows the regiospecific synthesis of a broad range of aryl- and heteroarylalkenes in high yields.
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