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Title: Visible-light photoredox-catalyzed synthesis of nitrones: unexpected rate acceleration by water in the synthesis of isoxazolidines. Author: Hou H, Zhu S, Pan F, Rueping M. Journal: Org Lett; 2014 Jun 06; 16(11):2872-5. PubMed ID: 24810928. Abstract: A new oxidative [3 + 2] cycloaddition of N-substituted hydroxylamines with alkenes was established under visible light photoredox catalysis. This novel protocol provides a rapid, mild, and efficient access to valuable five-membered ring isoxazolidine heterocycles in a concise fashion.[Abstract] [Full Text] [Related] [New Search]