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  • Title: Enantioselective synthesis of benzazepinoindoles bearing trifluoromethylated quaternary stereocenters catalyzed by chiral spirocyclic phosphoric acids.
    Author: Li X, Chen D, Gu H, Lin X.
    Journal: Chem Commun (Camb); 2014 Jul 18; 50(56):7538-41. PubMed ID: 24890313.
    Abstract:
    The first highly enantioselective iso-Pictet-Spengler reaction of C-2-linked o-aminobenzylindoles with trifluoromethyl ketones was developed using chiral spirocyclic phosphoric acids as organocatalysts, which afforded optically active benzazepinoindoles bearing trifluoromethylated quaternary stereocenters.
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