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  • Title: Palladium-catalyzed oxidative cyclization of tertiary enamines for synthesis of 1,3,4-trisubstituted pyrroles and 1,3-disubstituted indoles.
    Author: Lian XL, Ren ZH, Wang YY, Guan ZH.
    Journal: Org Lett; 2014 Jun 20; 16(12):3360-3. PubMed ID: 24922082.
    Abstract:
    A novel and efficient palladium-catalyzed intramolecular oxidative cyclization of tertiary enamines for the synthesis of 1,3,4-trisubstituted pyrroles and 1,3-disubstituted indoles has been developed. Trifluoroacetic acid plays an important role in the reaction. A series of pyrroles and indoles with substitution patterns that are not easily accessible by traditional routes were synthesized in good yields under mild conditions.
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